Product ID:CS-40 ALKALINITY CONTROL AGENT
MSDS Date:07/23/1991
FSC:6850
NIIN:00N043477
MSDS Number: BRSHC

ROCHESTER MIDLAND

ROCHESTER, NY 14603-1515
US

Emergency Phone: 716-266-2283

Info Phone: 716-336-2200

Cage: 24534

ROCHESTER MIDLAND CORP. DOLGE C B CO DIV

1515 ROCHESTER, NY 14603-1515 US

Telephone: 716-336-2200/716-266-2250

Cage: 24534

SULFURIC ACID (SARA III)

CAS: 7664-93-9

RTECS: WS5600000

Fraction By Weight: 50%

OSHA PEL 1 MG/M3

ACGIH TLV: 1 MG/M3, 3 STEL

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

1) (SARA III). (PEL & TLV GIVEN AS ZNO)

CAS: 7733-02-0

RTECS: ZH5260000

Fraction By Weight: 1.4%(ZN)

OSHA PEL 5 MG/M3,10 STEL

ACGIH TLV: 5 MG/M3,10 STEL

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

PHOSPHORIC ACID, (NITRILOTRIS(METHYLENE))TRI-; (AMINO

CAS: 6419-19-8

RTECS: SZ9860000

Fraction By Weight: 5-10%

OSHA PEL N/K

ACGIH TLV: N/K

SODIUM TOLYLTRIAZOLE

CAS: 64665-57-2

Fraction By Weight: 1-5%

OSHA PEL N/K

ACGIH TLV: N/K

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE: CORROSIVE; CAUSES SEVERE BURNS
TO EYES, AND MUCOUS MEMBRANE. SKIN: POSSIBLE SEVERE BURNS.
INHALATION OF SPRAY MIST IRRITATING TO NOSE AND THROAT; MAY CAUSE
TISSUE DAMAGE. INGEST: MAY BE FATAL; SWELLING AND TISSUE DAMAGE TO
MOUTH, THROAT AND ESOPHAGUS. CHRONIC: NONE KNOWN.
Explanation of Carcinogenicity:SULFURIC ACID: IARC MONOGRAPHS ON THE
EVALUATION OF CARCINOGEN RISK OF CHEMICALS TO MAN, VOL 54, PG 41,
1992: GROUP 1.
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:RESPIRATORY (FROM INHALATION OF
MIST).

First Aid:EYE/SKIN: FLUSH IMMEDIATELY WITH WATER FOR AT LEAST 15 MIN.
REMOVE CONTAMINATED CLOTHING. INHAL: REMOVE TO FRESH AIR. INGEST:
DO NOT INDUCE VOMITING. IF CONSCIOUS, GIVE WATER OR MILK TO DILUTE.
IN ALL CASES, GET IMMEDIATE MEDICAL ATTENTION.

Flash Point:NONE
Extinguishing Media:PROD WILL NOT BURN. USE CARBON DIOXIDE OR DRY CHEM
ON SURROUNDING FIRE; OR USE WATER W/EXTREME CARE, AS WATER (SUPP
DATA
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT . AVOID EXPOSURE TO MISTS AND SPLASHES. COOL
STORAGE DRUMS WITH WATER SPRAY.
Unusual Fire/Explosion Hazard:AS ANY STRONGLY ACIDIC SOLUTION, CAN
REACT WITH METALS TO GENERATE HYDROGEN. THIS GAS IS FLAMMABLE
AND/OR EXPLOSIVE IN THE PRESENCE OF AN IGNITION SOURCE.

Spill Release Procedures:CLEANUP PERSONNEL SHOULD WEAR APPROPRIATE
PROTECTIVE EQUIPMENT. COVER SPILL AREA WITH SODIUM BICARBONATE OR
SODA ASH. MIX WITH WATER TO FORM A SLURRY. SCOOP UP SLURRY AND
DISPOSE. WASH RESIDUES AWAY W ITH LARGE AMOUNTS OF WATER.
Neutralizing Agent:SEE WASTE DISPOSAL METHOD.

Handling and Storage Precautions:DO NOT MIX W/CHLORINE CONTAINING
COMPOUNDS. KEEP CONTAINER CLOSED. STORE AS AN ACID MATL, IN A COOL,
DRY AREA AWAY FROM OXIDIZERS OR COMBUST MATLS.
Other Precautions:DO NOT REUSE EMPTY CONTAINERS; WASH OUT THOROUGHLY
WITH WATER AND DISCARD. KEEP OUT OF REACH OF CHILDREN. DO NOT GET
IN EYES, ON SKIN OR CLTHG. DO NOT BREATHE MIST/VAPORS. READ &
FOLLOW LABEL DIRECTIO NS. WHEN MAKING A SOLN, ADD (SUPP DATA)

Respiratory Protection:NOT NORMALLY REQUIRED. NIOSH/MSHA APPROVED ACID
RESPIRATOR IF MIST IN AIR EXCEEDS EXPOSURE LIMITS.
Ventilation:NOT NORMALLY NEEDED. LOCAL EXHAUST WITH CORROSION RESISTANT
EQUIPMENT IF MIST IN AIR.
Protective Gloves:PLASTIC OR RUBBER.
Eye Protection:CHEM SFTY GOG & FULL LNGTH FSHLD .
Other Protective Equipment:RUBBER OR PLASTIC TO PREVENT SKIN CONTACT.
EMERGENCY EYEWASH AND DELUGE SHOWER .
Work Hygienic Practices:WASH SKIN THOROUGHLY AFTER HANDLING. REMOVE AND
WASH CONTAMINATED GLOVES AND CLOTHING BEFORE REUSE.
Supplemental Safety and Health
EXTING MEDIA: APPLIED DIRECTLY TO SULFURIC ACID SOLUTION MAY RESULT IN
GENERATION OF HEAT AND CAUSES SPATTERING. OTHER PREC: SLOWLY TO
SURFACE OF SOLUTION TO AVOID SPATTERING.

HCC:C1
Boiling Pt:B.P. Text:212F,100C
Vapor Pres:AS WATER
Vapor Density:AS WATER
Spec Gravity:1.3
pH:< 1
Evaporation Rate & Reference:SLOWER THAN ETHER
Solubility in Water:COMPLETE
Appearance and Odor:CLEAR OFF-WHITE TO YELLOW LIQUID, NO ODOR.
Percent Volatiles by Volume:55

Stability Indicator/Materials to Avoid:YES
DO NOT MIX WITH ALKALINE SOLUTIONS. AVOID CONTACT WITH METALS, ORGANIC
MATLS, OR COMBUST EXCEPT I/A/W USE DIRECTIONS.
Stability Condition to Avoid:NONE.
Hazardous Decomposition Products:OXIDES OF SULFUR.

Waste Disposal Methods:TRAINED AND PROPERLY EQUIPPED PERSONNEL MAY
DILUTE AND NEUTRALIZE WASTE VERY CAREFULLY WITH DILUTE ALKALI IN
ACCORDANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.